On Saturday, trucks laden with US food and medicine on the Colombian border repeatedly attempted to push past lines of troops but were met with tear gas and rubber bullets.
Two of the aid trucks went up in flames, which the opposition blamed on security forces and the government on “drugged-up protesters”.
The Brazilian border state of Roraima said the number of Venezuelans being treated for gunshot wounds rose to 18 from five in the past 24 hours; all 18 were in serious condition.
That was the result of constant gun battles, which included armed men without uniforms, throughout Saturday in the Venezuelan town of Santa Elena, near the border.
The Venezuelan Observatory of Violence, a local crime monitoring group, said it had confirmed three deaths on Saturday, all in Santa Elena, and at least 295 injured across the country.
In the Venezuelan city of Urena on the border with Colombia, streets were still strewn with debris on Sunday, including the charred remains of a bus that had been set ablaze by protesters.
UN Secretary-General Antonio Guterres appealed on Sunday for “violence to be avoided at any cost” and said everyone should lower tensions and pursue efforts to avoid further escalation, according to his spokesman.
The European Union has also condemned the use of violence and armed civilian groups to block the entry of aid.
“We repudiate the use of irregular armed groups to intimidate civilians and lawmakers who have mobilized to distribute assistance,” said Federica Mogherini, EU foreign policy chief.